Abstract
The objective was to study the degradation of azo dye C.I. Acid Orange 7 (AO7) and intermediates for its synthesis sulphanilic
acid (SA) and 2-naphthol (2-N) by Fenton process. Full factorial design and response surface methodology were applied to model
the system behavior influenced by studied process parameters ([Fe2+] and [H2O2]).
Optimal process conditions were determined on the basis of mineralization efficiency. The effectiveness evaluation of applied
treatment process was conducted on the basis of UV/VIS, TOC, COD, BOD5 and toxicity measurements. Fenton reagent ratio
1:62-68 ([Fe2+]≈1.5 mM and [H2O2]=100 mM) yielded the highest TOC reductions for AO7, SA and 2-N (53 %, 44 % and 52 %,
respectively), along with the complete decolorization of azo dye solution and degradation of aromatic fragments in solutions after
60-min treatment.
Three synthetic wastewaters are characterized as non-biodegradable before Fenton treatment (BOD5/COD≤0.22). After 60-min
treatment biodegradability of all three wastewaters was improved; BOD5/COD ratios ranged from 0.38 to 0.52. The values of
EC50 showed that all pollutants in investigated concentrations are toxic, while remarkable toxicity reduction after the treatment
was noticed only in the case AO7; in the case of other two pollutants the formation of toxic by-products can be assumed.